Data di Pubblicazione:
2023
Citazione:
Catenated covalent organic frameworks constructed from polyhedra / T. Ma, Y. Zhou, C.S. Diercks, J. Kwon, F. Gándara, H. Lyu, N. Hanikel, P. Pena-Sánchez, Y. Liu, N.J. Diercks, R.O. Ritchie, D.M. Proserpio, O. Terasaki, O.M. Yaghi. - In: NATURE SYNTHESIS. - ISSN 2731-0582. - (2023 Jan 16). [10.1038/s44160-022-00224-z]
Abstract:
Although the synthetic chemistry leading to interlocking molecular [n]
catenanes of organic polyhedra (n = 2–3) and rings (n = 2–130) is established,
the analogous chemistry that pertains to infinite three-dimensional
systems ([∞]catenane) remains undeveloped. We report a series of [∞]
catenane covalent organic frameworks (termed catena-COFs). These were
synthesized by linking 4 ,4′-(1,10-phenanthroline-2,9-diyl)dibenzaldehyde
to either of tris-(4-aminophenyl)-amine, -methane or -methanol through
imine condensation. These combinations give discrete adamantane-like
polyhedra, catenated by virtue of the copper(I) ions templating a mutually
embracing arrangement of PDBs (points-of-catenation), which ultimately
results in infinite catena-COF-805, 806 and 807. The crystal structures of
these COFs obtained from electron microscopy and X-ray diffraction were
determined to be isoreticular and to adopt the bor-y structure type.
Tipologia IRIS:
01 - Articolo su periodico
Keywords:
covalent organic frameworks; catenation
Elenco autori:
T. Ma, Y. Zhou, C.S. Diercks, J. Kwon, F. Gándara, H. Lyu, N. Hanikel, P. Pena-Sánchez, Y. Liu, N.J. Diercks, R.O. Ritchie, D.M. Proserpio, O. Terasaki, O.M. Yaghi
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