Data di Pubblicazione:
2022
Citazione:
Coordination chemistry of hepta-tert-butylnonaphosphane / V. Jens Eilrich, T. Grell, P. Lönnecke, E. Hey-Hawkins. - In: DALTON TRANSACTIONS. - ISSN 1477-9226. - 51:29(2022), pp. 10887-10897. [10.1039/D2DT01691E]
Abstract:
Hepta-tert-butylnonaphosphane {cyclo-(P4tBu3 )}2 PtBu was employed as a ligand in transition metal com-
plexes of iron(0) (1), cobalt(−I) (2), copper(I) (3) and rhodium(I) (4), which are readily formed in moderate
to good yields, and an unstable palladium(II) complex (5). The ligand features three different bonding
modes (one monodentate (compounds 1 and 2) and two bidentate (compounds 3–5) with formation of
four- or six-membered chelate rings), as determined by X-ray diffraction studies. The 31
P{ 1H} NMR spectral data of 1–3 have been determined by automated line-shape analysis.
Tipologia IRIS:
01 - Articolo su periodico
Elenco autori:
V. Jens Eilrich, T. Grell, P. Lönnecke, E. Hey-Hawkins
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