Comparative performance of copper and iron functionalized hydroxyapatite catalysts in NH3-SCR
Articolo
Data di Pubblicazione:
2019
Citazione:
Comparative performance of copper and iron functionalized hydroxyapatite catalysts in NH3-SCR / S. Campisi, M.G. Galloni, F. Bossola, A. Gervasini. - In: CATALYSIS COMMUNICATIONS. - ISSN 1566-7367. - 123(2019 Apr), pp. 79-85.
Abstract:
Iron-functionalized hydroxyapatite (Fe/HAP, 2 < Fe wt% < 7) was prepared by ionic exchange and tested in
the NOx reduction by ammonia (NH3-SCR). Iron dispersion, structure and acidity of the samples were investigated
by UV–vis-DR spectroscopy, XRPD and ammonia titration. On Fe/HAP catalysts, NOx conversion
started at higher temperatures and was always lower than on the reference Cu/HAP catalysts. Selectivity to N2
was remarkable (> 95%) up to the attainment of maximum NOx conversion; for higher temperatures, selectivity
declined due to the formation of N2O from NH3 over-oxidation. TPR-TPO cycles allowed to relate the redox
properties of samples with their catalytic performances
Tipologia IRIS:
01 - Articolo su periodico
Keywords:
Hydroxyapatite; Iron functionalized hydroxyapatite; NH3-SCR catalysts
Elenco autori:
S. Campisi, M.G. Galloni, F. Bossola, A. Gervasini
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