Enantioselective allylation of aldehydes with allyltrichlorosilane promoted by new chiral dipyridylmethane N-oxides
Articolo
Data di Pubblicazione:
2007
Citazione:
Enantioselective allylation of aldehydes with allyltrichlorosilane promoted by new chiral dipyridylmethane N-oxides / G. Chelucci, N. Belmonte, M. Benaglia, L. Pignataro. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - 48:23(2007), pp. 4037-4041.
Abstract:
New chiral dipyridine N-monoxides and N,N′-dioxides, which possess an isopropylidene backbone between two pyridine rings, have been prepared from naturally occurring monoterpenes. Their utility as organocatalysts has been demonstrated in the enantioselective addition of allyltrichlorosilane to aldehydes. Enantioselectivities up to 85% ee have been obtained.
Tipologia IRIS:
01 - Articolo su periodico
Keywords:
Chiral N-oxides ; Enantioselective organocatalysis ; Allylation ; Dipyridylmethane ligands ; Allyltrichlorosilanes
Elenco autori:
G. Chelucci, N. Belmonte, M. Benaglia, L. Pignataro
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