Synthesis, crystal structure and crystal chemistry of ferri-clinoholmquistite, □Li2Mg3 Fe3+2Si8O22(OH)2
Articolo
Data di Pubblicazione:
2004
Citazione:
Synthesis, crystal structure and crystal chemistry of ferri-clinoholmquistite, □Li2Mg3 Fe3+2Si8O22(OH)2 / G. Iezzi, F. Cámara, G. Della Ventura, R. Oberti, G. Pedrazzi, J.L. Robert. - In: PHYSICS AND CHEMISTRY OF MINERALS. - ISSN 0342-1791. - 31:6(2004 Jul), pp. 375-385.
Abstract:
This work reports the synthesis of ferri-clinoholmquistite, nominally □Li2(Mg3Fe3+2) Si8O22(OH)2, at varying fO2 conditions. Amphibole compositions were characterized by X-ray (powder and single-crystal) diffraction, microchemical (EMPA) and spectroscopic (FTIR, Mössbauer and Raman) techniques. Under reducing conditions (≤ NNO+1, where NNO = Nickel-Nickel oxide buffer), the amphibole yield is very high (>90%), but its composition, and in particular the FeO/Fe2O3 ratio, departs significantly from the nominal one. Under oxidizing conditions (≤ NNO+1.5), the amphibole yield is much lower (<60%, with Li-pyroxene abundant), but its composition is close to the ideal stoichiometry. The exchange vector of relevance for the studied system is M2(Mg, Fe2+) M4(Mg, Fe2+) M2Fe3+-1M4Li-1, which is still rather unexplored in natural systems. Amphibole crystals of suitable size for structure refinement were obtained only at 800 °C, 0.4 GPa and NNO conditions (sample 152), and have C2/m symmetry. The X-ray powder patterns for all other samples were indexed in the same symmetry; the amphibole closest to ideal composition has a = 9.428(1) Å b = 17.878(3) Å c = 5.282(1) Å, β = 102.06(2)°, V = 870.8(3) Å3. Mössbauer spectra show that Fe3+ is strongly ordered at M2 in all samples, whereas Fe2+ is disordered over the B and C sites. FTIR analysis shows that the amount of CFe2+ increases for increasingly reducing conditions. FTIR data also provide strong evidence for slight but significant amounts of Li at the A sites.
Tipologia IRIS:
01 - Articolo su periodico
Keywords:
Infrared and Mössbauer spectroscopy; Microprobe analysis; Short-range order; Structure refinement; Synthetic ferri-clinoholmquistite
Elenco autori:
G. Iezzi, F. Cámara, G. Della Ventura, R. Oberti, G. Pedrazzi, J.L. Robert
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