Data di Pubblicazione:
2001
Citazione:
High-pressure structural behaviour of heulandite / P. Comodi, G.D. Gatta, P.F. Zanazzi. - In: EUROPEAN JOURNAL OF MINERALOGY. - ISSN 0935-1221. - 13:3(2001), pp. 497-505. [10.1127/0935-1221/2001/0013-0497]
Abstract:
The structural evolution up to 5 GPa of a natural heulandite was studied using in situ single-crystal X-ray diffraction data from a diamond-anvil cell (DAC) with glycerol as the pressure transmitting medium. Linear regressions yielded mean axial compressibilities for a, b and c axes of βa = 1.02(1). 10-2, βb = 7.6(2). 10-3 GPa-1. The largest strain vector (β1 = 1.16 10-2 GPa-1)lies approximately on the diagonal of the system of channels along [100] and [001]. V0, K0, and K0' refined with a third-order Birch-Murnaghan equation are: V0 = 2121(2) Å3, K0 = 26.4(1.0) GPa, K0' = 4.9(8). If fitted with second-order Birch-Murnaghan equation of state, fixing K0' = 4, K0 becomes 27.5(2) GPa. The bulk heulandite structure compression was the result of the "soft" behaviour of the channels (K = 10-19 GPa) and the more rigid behaviour of the tetrahedral framework (K ≅ 60 GPa), which underwent tilting of the fundamental polyhedral unit (FPU) chains. The T5-T5-T5 angles, between the FPUs, decreased from 162.4° at 0.0001 GPa to 156.2° at 3.4 GPa. The position of extra-framework cations and water molecules was almost maintained within the investigated pressure range. Up to 3.7 GPa no phase transition was observed. Amorphization was clearly observed at pressure above 4 GPa. The transition to the amorphous phase was still reversible up to 5 GPa.
Tipologia IRIS:
01 - Articolo su periodico
Keywords:
zeolite; heulandite; single-crystal X-ray diffraction; high pressure; compressibility
Elenco autori:
P. Comodi, G.D. Gatta, P.F. Zanazzi
Link alla scheda completa: