Data di Pubblicazione:
1987
Citazione:
CATALYTIC ASYMMETRIC WEITZ-SCHEFFER EPOXIDATION PROMOTED BY BOVINE SERUM-ALBUMIN .2 / S. COLONNA, A. MANFREDI, R. ANNUNZIATA, M. SPADONI. - In: TETRAHEDRON. - ISSN 0040-4020. - 43:9(1987), pp. 2157-2164. [10.1016/S0040-4020(01)86797-1]
Abstract:
The epoxidation of 2 and 2,3-substituted naphthoquinones with t-BuOOH in aqueous buffer solutions, in the presence of bovine serum albumin (BSA) as chiral catalyst, affords the corresponding epoxynaphthoquinones with enantiomeric excess (e.e.) up to 79%. The influences on the enantioselectivity of the pH of the buffer solution, of the oxidizing agent, and of inorganic salts have also been examined.
Tipologia IRIS:
01 - Articolo su periodico
Elenco autori:
S. Colonna, A. Manfredi, R. Annunziata, M. Spadoni
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