Data di Pubblicazione:
2006
Citazione:
Organic yield of 37Cl(n,gamma)38Cl in binary mixtures of CCl4 and alcohols / Z.B. Alfassi, F. Groppi. - In: JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY. - ISSN 0236-5731. - 268:3(2006 Jun), pp. 613-616.
Abstract:
PERTESSIS-KEIS has studied the yield of organic 38Cl from the reaction 37Cl(n,g)38Cl in binary mixtures of CCl4 and alcohols. KONTIS and URCH
suggested an independent binary model to interpret the data, however, none of their data agree with the model over the whole range of
concentrations. In this paper we suggest a new model based on the formation of organic 38Cl by two precursors, one independent on the media
(failure to bond rupture), while the other depends on the concentration of the two components in the binary mixture (reactions of hot and
thermalized 38Cl). Our model fits all the alcohols studied by PERTESSIS-KEIS1,2 over the whole range of concentration.
A plot of 1/(Y0–Y) vs. mA/mB was found to be a straight line for all the six
alcohols studied by PERTESSIS-KEIS
Tipologia IRIS:
01 - Articolo su periodico
Keywords:
RECOIL CHLORINE ; CARBON-TETRACHLORIDE ; CL-38 ; CHLOROBENZENE ; PARAFFINS ; ETHANOL
Elenco autori:
Z.B. Alfassi, F. Groppi
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